Kinetic and safety assessment for salicylic acid nitration by nitric acid/acetic acid system.

نویسندگان

  • R Andreozzi
  • V Caprio
  • I Di Somma
  • R Sanchirico
چکیده

The nitration process of salicylic acid for the production of the important intermediate 5-nitrosalicylic acid is studied from thermokinetic and safety points of view. Investigations carried out by considering, as process deviations, the loss of the thermal control point out the possibility of runaway phenomena due to the occurrence of polynitration reactions. Isothermal experiments are carried out in various conditions to assess the involved reaction network and reaction kinetics.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

HNO3/N,N-Diethylethanaminium-2-(Sulfooxy)Ethyl Sulfate as an Efficient System for the Regioselective of Aromatic Compounds

N,N-diethylethanaminium-2-(sulfooxy) ethyl sulfate was synthesized and used as  an efficient, green, and recyclable catalyst and solvent for the nitration of aromatic compounds by nitric acid at 80oC

متن کامل

COMPARISON OF PHYSIOLOGICAL AND BIOCHEMICAL RESPONDS BETWEEN TWO VARIETIES OF Glycyrrhiza glabra TO MOLYBDENUM AND SALICYLIC ACID

To investigate responses of Glycyrrhiza glabra var. glabra and G. glabra var. glandulifera to molybdenum and salicylic acid, we measured four stress biochemical parameters: anthocyanin, nitric acid, glycyrrhizic acid and peroxidase activity in callus tissues. Callus tissues obtained from seedlings root cultures were treated by 60 mg. l-1 molybdenum and 5 µM salicylic acid alone or together for...

متن کامل

Synthesis of Ammonium Dinitramide by Nitration of Potassium and Ammonium Sulfamate. The Effect of Sulfamate Conterion on ADN Purity

Nitration of potassium sulphamate was carried out using a mixture of sulphuric and nitric acid at -30 °C. The reaction time was optimized at the mole ratio of sulphuric to nitric acid of (1:3.5). The difference in product yield by changing the potassium to ammonium sulphamate was studied throughly. It was found that both the yield and purity of the product is better starting with potassium ...

متن کامل

Effect of Salicylic Acid on Somatic Embryogenesis and Chlorogenic Acid Levels of Carrot (Daucus carota cv. Nantes) Explants

Many factors may influence the efficiency of somatic embryogenesis. This capability may be differ with regard to media compositions, genotype, tissue, organ ontology and the stage of differentiation. The effects of five salicylic acid concentrations (0, 25, 50, 75 and 100 mM) on different stages of carrot somatic embryogenesis were studied using petiole and root secondary phloem explants as sta...

متن کامل

Growth limits of Staphylococcus aureus as a function of temperature, acetic acid, NaCl concentration, and inoculum level

Staphylococcus aureus is one of the most prevalent causes of gastroenteritis worldwide. Knowing the precise boundary for the growth/no growth interface of S. aureus and also determining the period of time needed for bacterial growth initiation is necessary for food safety risk assessment. This study was designed to examine the combined effects of temperature, acetic acid, inoculum level and NaC...

متن کامل

ذخیره در منابع من

ذخیره در منابع من قبلا به منابع من ذحیره شده

{@ msg_add @}


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Journal of hazardous materials

دوره 134 1-3  شماره 

صفحات  -

تاریخ انتشار 2006